<el-form :model="dynamicValidateForm" ref="dynamicValidateForm" label-width="100px" class="demo-dynamic">
  <el-form-item
    v-for="(domain, index) in dynamicValidateForm.domains"
    :label="'域名' + index"
    :key="domain.key"
    :prop="'domains.' + index + '.value'"
    :rules="{
      required: true, message: '域名不能为空', trigger: 'blur'
    }"
  >
    <el-select v-model="dynamicValidateForm.domains[index]" placeholder="选择">
    <el-option
      v-for="item in options"
      :key="item"
      :label="item.label"
      :value="item.value">
    </el-option>
  </el-select>
    <el-button @click.prevent="removeDomain(domain)">删除</el-button>
  </el-form-item>
  <el-form-item>
    <el-button type="primary" @click="submitForm('dynamicValidateForm')">提交</el-button>
    <el-button @click="addDomain">新增域名</el-button>
    <el-button @click="resetForm('dynamicValidateForm')">重置</el-button>
  </el-form-item>
</el-form>

<script>
  export default {
    data() {
      return {
                options: [{
          value: '选项1',
          label: '黄金糕'
        }, {
          value: '选项2',
          label: '双皮奶'
        }, {
          value: '选项3',
          label: '蚵仔煎'
        }, {
          value: '选项4',
          label: '龙须面'
        }, {
          value: '选项5',
          label: '北京烤鸭'
        }],

        }
      };
    },
    methods: {
      submitForm(formName) {
        this.$refs[formName].validate((valid) => {
          if (valid) {
            alert('submit!');
          } else {
            console.log('error submit!!');
            return false;
          }
        });
      },
      resetForm(formName) {
        this.$refs[formName].resetFields();
      },
      removeDomain(item) {
        var index = this.dynamicValidateForm.domains.indexOf(item)
        if (index !== -1) {
          this.dynamicValidateForm.domains.splice(index, 1)
        }
      },
      addDomain() {
        this.dynamicValidateForm.domains.push({
          value: '',
          key: Date.now()
        });
      }
    }
  }
</script>

只需更改select的 v-model绑定即可