我用他的方法解决了问题,亲测可用,不要用Navicat for Mysql去查询编码,
在服务器中以root命令进入mysql,用show variables like 'char%';命令查询的编码才是最准确的.

㈠ 序言

为了应对无线互联网的机遇和挑战、避免 emoji 表情符号带来的问题、

涉及无线相关的 MySQL 数据库建议都提前采用 utf8mb4 字符集

这必须要作为移动互联网行业的一个技术选型的要点

㈡ 限制

需要 >= MySQL 5.5.3版本、从库也必须是5.5的了、低版本不支持这个字符集、复制报错

㈢ 简要步骤

以下是一个未升级到 5.5.3 的配置步骤：

① 备份数据库

② 升级 MySQL Server 到 v5.5.3+

③ 修改 database、table和column字符集

For each database:
ALTER DATABASE database_name CHARACTER SET = utf8mb4 COLLATE = utf8mb4_unicode_ci;
# For each table:
ALTER TABLE table_name CONVERT TO CHARACTER SET utf8mb4 COLLATE utf8mb4_unicode_ci;
# For each column:
ALTER TABLE table_name CHANGE column_name column_name VARCHAR(191) CHARACTER SET utf8mb4 COLLATE utf8mb4_unicode_ci;
# (Don’t blindly copy-paste this! The exact statement depends on the column type, maximum length, and other properties. The above line is just an example for a `VARCHAR` column.)

④ 修改 my.cnf

[client]
default-character-set = utf8mb4

[mysql]
default-character-set = utf8mb4

[mysqld]
character-set-client-handshake = FALSE
character-set-server = utf8mb4
collation-server = utf8mb4_unicode_ci
init_connect='SET NAMES utf8mb4'

⑤ 重启 MySQL Server、检查字符集

mysql> SHOW VARIABLES WHERE Variable_name LIKE 'character\_set\_%' OR Variable_name LIKE 'collation%';
+--------------------------+--------------------+
| Variable_name            | Value              |
+--------------------------+--------------------+
| character_set_client    | utf8mb4            |
| character_set_connection | utf8mb4            |
| character_set_database  | utf8mb4            |
| character_set_filesystem | binary            |
| character_set_results    | utf8mb4            |
| character_set_server    | utf8mb4            |
| character_set_system    | utf8              |
| collation_connection    | utf8mb4_unicode_ci |
| collation_database      | utf8mb4_unicode_ci |
| collation_server        | utf8mb4_unicode_ci |
+--------------------------+--------------------+
 rows in set (0.00 sec)

http://www.linuxidc.com/Linux/2013-05/84360.htm

MySQL 如何修改 utf8mb4 字符集

修改库：    
ALTER DATABASE database_name CHARACTER SET = utf8mb4 COLLATE = utf8mb4_unicode_ci;
修改表:
ALTER TABLE table_name CONVERT TO CHARACTER SET utf8mb4 COLLATE utf8mb4_unicode_ci;
修改一列:
ALTER TABLE table_name CHANGE column_name column_name VARCHAR(191) CHARACTER SET utf8mb4 COLLATE utf8mb4_unicode_ci;